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Class 12 Chemistry MCQ Chapter 13 Amines
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Amines
Chapter: 13
MCQ |
1. What type of amine is formed when two hydrogen atoms of ammonia are replaced?
(i) Primary amine.
(ii) Secondary amine.
(iii) Tertiary amine.
(iv) Quaternary amine
Ans: (ii) Secondary amine.
2. Which of the following amine-based compounds is used as a local anaesthetic in dentistry?
(i) Ephedrine.
(ii) Novocain.
(iii) Benadryl.
(iv) Adrenaline.
Ans: (ii) Novocain.
3. At what temperature is diazotisation carried out for the formation of diazonium salts?
(i) 293–298 K
(ii) 250–270 K
(iii) 273–278 K
(iv) 300–310 K
Ans: (iii) 273–278 K
4. Nitrogen atom of amino group is ………. hybridised.
(i) sp
(ii) sp2
(iii) sp3
(iv) sp3d
Ans: (iii) sp3
5. The compound which on reaction with aqueous nitrous acid at low temperature produces an oily nitrosamine is:
(i) Methyl amine.
(ii) Diethyl amine.
(iii) Ethyl amine.
(iv) Triethyl amine.
Ans: (iv) Triethyl amine.
6. Ethylamine can be prepared by the action of bromine and caustic potash on:
(i) Acetamide.
(ii) Formamide.
(iii) Propionamide.
(iv) Methyl cyanide.
Ans: (i) Acetamide.
7. Which of the following amines can exhibit enantiomerism?
(i) Benzenamine.
(ii) 2-Butanamine.
(iii) 2-Propanamine.
(iv) 2-Methyl-propanamine.
Ans: (ii) 2-Butanamine.
8. What are diazonium salts mainly used for in chemical reactions?
(i) Synthesis of alkanes.
(ii) Preparation of aromatic compounds and dyes.
(iii) Production of alcohols.
(iv) Formation of esters.
Ans: (ii) Preparation of aromatic compounds and dyes.
9. Reaction of an aliphatic primary amine with nitrous acid in cold leads to the formation of:
(i) A nitrile.
(ii) An alcohol.
(iii) A diazonium salt.
(iv) A secondary amine.
Ans: (ii) An alcohol.
10. What is the product when an amide is reduced with lithium aluminium hydride (LiAlH₄)?
(i) Ketone
(ii) Amine
(iii) Alcohol
(iv) Aldehyde
Ans: (ii) Amine
11. Amongst the following, the most basic compound is:
(i) Benzylamine.
(ii) Aniline.
(iii) Acetanilide.
(iv) p-Nitroaniline.
Ans: (i) Benzylamine.
12. What is the major product when butanamide undergoes Hoffmann bromamide degradation?
(i) Ethylamine.
(ii) Methylamine.
(iii) Propanamine.
(iv) Butylamine.
Ans: (iii) Propanamine.
13. Which reagent is used for the reduction of amides to amines?
(i) LiAlH₄
(ii) H₂/Pd
(iii) NaBH₄
(iv) Grignard reagent
Ans: (i) LiAlH₄
14. Which compound is more soluble in water?
(i) Butan-1-ol.
(ii) Butan-1-amine.
(iii) Both are equally soluble.
(iv) Neither is soluble.
Ans: (i) Butan-1-ol.
15. Benzene diazonium chloride when reacts with hypophosphorous acid produces :
(i) Benzene.
(ii) Phenol.
(iii) Phenyl phosphite.
(iv) Phenyl phosphate.
Ans: (i) Benzene.